Sunday, June 29, 2014

On Silent Haunches

Just a quick update: we have fog!! We just began sampling up here at the station, and of course - as soon as I connected the sample bottles, the liquid water content went back to almost zero. But it's back! This is a really nice event: most of the fog we've observed so far at the station has been short-lived and patchy. However, this one started around 3:30 am, and has lasted at least until now ---around 6 am. Jeongmin (I think I've been misspelling his name - sorry!) called me around 4:00 to say that there was fog in town, so we turned on the CASCC2 at the dormitories. When we got back, this is what I found on the PVM computer.


The signal was up to 90 mg liquid water per cubic meter of air, which is, I think, the highest I've seen so far! The ride down here in the car was a little dodgy because the fog was also dense on the road. When we arrived, the fog had lasted --last time, we arrived and the event ended just then. You can see at about 5:05 am, when I connected the sample bottles, the signal dropped - I thought for sure we were out of luck a second time. But the LWC rose back up, and I saw about 144 mg per cubic meter on the screen at one point. This is a great morning for fog!


To capture the moment, here's an image of the sf-CASCC in action.


And me with it!


One last note: while excitedly drinking my "coffee" a few minutes ago, I googled a poem about fog that we learned in choir when I was in middle school. We all made fun of it at the time because the song was sort of weird, but it turns out it was written by Carl Sandburg, who was born in the town where I went to college (go Knox!).

Fog
The fog comes
on little cat feet.

It sits looking
over harbor and city
on silent haunches
and then moves on.

Friday, June 27, 2014

백령도 (Baengnyeongdo)

Success! We're on the island, our boxes arrived, we set everything up, and now we have collected 1.25 fog water samples! The three of us students have learned the ropes from Dr. Taehyoung Lee, my host professor, and Cheong Min and I are on our own, collecting samples 24 hours per day! We have one fog water collector set up at our originally planned site, at the weather and atmospheric research station on the other end of the island (about a 35 min drive). The other collector has been moved to the dormitory for the station employees, here in Jinchon because we have been getting fog events in the town, but not at the high elevation of the station. We've gotten one large sample (~100 mL) and one smaller sample (~2 mL) from the collector in town, but have not had luck yet with the station collector. As I'm writing this blog entry, I'm at the station (it's 1:28 am on Saturday morning) because the liquid water detector showed fog, but it seems to have dissipated now that we've arrived. The fog events at the station are shorter so far, maybe because the water is lofted with somewhat higher winds to our site, which quickly blow the fog away. Hopefully we'll see some deeper fog before the end of our campaign!

The station has a really nice view from the top deck, where we set up our instruments. On the left in the back is our large fog/cloud water collector, the size fractionated Caltech Active Strand Cloudwater Collector (sf-CASCC). The black spots on the ends are bags, which prevent particles from getting into the collector while it's not operating. Our smaller collector, the CASCC-2 (with only one size fraction) is on the right. In the back you might be able to distinguish a white instrument shaped like an angry crab --that's our liquid water detector, the Particulate Volume Monitor (PVM). The rest of the instrument up here belong to the station, and are permanent installments. It's a pretty well equipped station! The building is run by the Korean National Institute for Environmental Research (NIER), and was established to characterize remote air masses.


To keep all our electrical connections out of the rain, we use multiple ziplock bags and lots of duct tape. I agree that it's probably necessary to keep this from getting wet, but it always makes me cringe a bit to be studying how to improve air and environmental quality, and be generating lots of waste. Somebody please get to work on enzymes that break down specific types of plastics to usable chemical products (not to name any names, Wil)!


I'm also trying something that's not in our fog/cloud water collection protocol: I'm collecting gas-phase carbonyls onto a passive sampler. Hopefully this will give us a handle on the approximate concentrations of possible reactants in the aqueous reactions I'm interested in. My sampler started out as this very simplistic setup, but the flow rate was unfortunately too low and the battery life too short using this little handheld air pump. The NIER scientists and my host advisor have helped me to improve this setup, and we're still working on it.


Here's our sf-CASCC, closer up. The red arrow marks the direction of flow. You can see that inside there are some thick, white Teflon rods to collect larger fog droplets as the fog enters the collector, then Teflon strands to collect the smaller droplets. While this looks at first glance to be a simple setup, this is an extremely efficient collector for this application. The water drains into collector bottles that we then weigh to determine approximate volume of sample collected, and divy out into small vials for chemical analyses. The rest of the sample is frozen for other tests, like my photoreactions that I've been focusing on in my research.


The PVM is certainly more complex, physically: it uses a light source in the IR range (780 nm) to generate measurable light refracted off of liquid water droplets (not vapor) at a particular angle. The resulting value is a liquid water content (LWC) in grams of liquid water per cubic meter of air. It's really nice because we can set it to run overnight, and watch for increased LWC at the station while we're in Jinchon at our motel. In daylight cases, it also helps to determine whether low visibility is due to particles or condensed water, and whether it is thick enough to be fog.


The view from the top of our research station, looking in all directions is really nice ---this is looking west, into some haze (particle-phase pollution, probably with some liquid condensing onto it since it's so humid here and there's lots of water-loving sea salt), which we often see.


This is the CASCC2, the smaller collector. You can see that there's only one "stage", the strands. These strands collect all the fog water pulled through the instrument into the bottle, instead of size-segregating like in our larger sf-CASCC.


Dr. Lee, Cheongmin and Seongweon (Seongweon isn't pictured here) also work with the aerosol mass spectrometer (AMS) at this site, which analyzes particle chemistry with ~minute time resolution: it tells us whether there's sea salt, sulfate, nitrate, and which types of organics in the particles. Their research lab is in charge of maintaining the AMS and PTR-MS instruments at several Korean government research sites. They also have set up a sizing instrument that can measure the number of particles with diameters as low as 5 nm (that's tiny!!). 


Here's Cheongmin working with the particle sizing instrument, which is called the nano scanning mobility particle sizer (nanoscan SMPS).


...And again, I can't get enough of the gorgeous sunsets, which are made especially colorful and eerie by the particles in the atmosphere here.



Here's us setting up the CASCC2 at the old tennis courts next to the NIER researchers' dormitories in Jinchon. We used ladders, which is what we could find that was high enough from the ground to be sampling mostly laminar flow, and also was sturdy. The collectors are surprisingly heavy. Dr. Lee (Taehyoung) is on the left, Cheongmin is in the back, and Seongweon is on the right.


Dr. Lee has been very welcoming about my seeing Korea, and has taken us to several nice places on this island. This one is an area of land that's filled with lotus plants. They're not blooming quite yet, but should be very soon. The houses in the background here as well as a store that's not pictured were hand-built by the man who planted the flowers.


We ate "ice flake" together, which is chipped ice, covered in delicious toppings like rice cakes and sweet red beans. There were also sprinkles and cereal.


The food here has been very good ---and although I really enjoy trying new foods and eating healthy (there's hardly any butter and mainly rice for carbs), we've gone out for pizza several times here and it's a real treat! This one is sweet potato pizza. To the left you can see the garlic cream and pickles they serve with pizza here. Although I figured I would need to start eating meat again here, my lab mates have been very kind in helping me to find vegetarian choices everywhere we go. I know that it's a burden to them, but they are very generous and every time I say that it's ok to have some meat, they find me another tasty choice without.


Ok, this is just about the worst transition ---food to nasty critters! This is a HUGE spider I saw on the windowsill (outside, thank goodness) at our motel. Its body is seriously about an inch in diameter, and legs at least another inch. My hand doesn't really allow for judging the size well, but SERIOUSLY! There are lots of bugs here at night, and I've been getting some bites on a regular basis. Haven't seen any mosquitos yet though...


...And back to food! This is probably my favorite dish so far. It's got good flavor, but mostly I appreciate that this so different, local, and subtle. It's a seafood soup, with lots of veggies and noodles. There's squid, shrimp, mussels, and maybe a few other items in there. Really tasty, and other than the noodles, really healthy. I don't usually like a lot of shellfish, but this is really tasty!


Yesterday, I decided to go for a run up to a sort of shrine that's been built to commemorate a folk legend that is said to have taken place on Baengnyeong Island. There's a nice view from the top, looking out into the Yellow Sea. This building is very beautiful, with images from the legend painted into the eaves, and bright colors all over. It's very similar to the buildings we saw in the ancient area of Gyeongju. The legend (as recounted by wikipedia) goes like this: a girl was born, and her mother died at child birth. She took care of her father, was blind, thereafter and was very kind. She heard that some fishermen would return her father's site if she would sacrifice herself to a sea king. She agreed, but the sea king was so moved by her actions that he returned her to life. She was returned within a lotus flower, to the emporer's palace. The emporer fell in love with her and married her, and she held a banquet for all blind men in the area. When her father saw her, he was so surprised he regained his sight. There are pictures and monuments all over the island commemorating this story.




I thought this statue of Cheong, the girl in the legend, was really beautiful.


Here are a couple shots of Jinchon on my way back down the mountain. It's a little touristy, but I have seen almost exclusively locals.



Here are some paintings of the legend, which are scattered throughout the town.



That's all for now! I have lots more time to spend on this island, and there are plenty more sites and places to go running before I can leave here. There will also be many more fog samples to collect! Nothing last night, but fingers crossed for a nice, big volume of fog water tonight!

Monday, June 23, 2014

The joys of a transit card

It's been a fun-filled week! Thanks to a very kind professor from Hankuk University of Foreign Studies, I learned to use the bus and got a transit card so I can travel around the Seoul area. Dr. Owen took me to Seongnam, which is a Seoul suburb of about 1 million people. There's lots of good shopping and ethnic foods. After being at HUFS for a week, even though it's a gorgeous campus, it was really nice to get into the city for a visit.

Here's a shot of Dr. Owen as we crossed the street to get to the shopping area "AK Plaza".


This is the restaurant where I got dinner, which was a Mexican restaurant with craft beers. This was one of about ten restaurants available in this food court (not attached to a mall).


In the bottom of a department store in AK Plaza, there was a fancy grocery store, which was fun to look around! This picture shows traditional tea ingredients (I don't think I could name any of these things, but they look interesting!).


The buildings in cities here are jam-packed full of stores on every floor. The signs litter the front of the buildings, and you can meander up the stairs and through the halls to find the store you're looking for. The view from the street is very colorful.


Some of the students in the natural sciences department at HUFS invited me to have pizza with them to celebrate one of the girls (second from the right) getting her PhD. Most of these students are studying wastewater treatment and soils science. The pizza was delicious ---it had a circle of sweet potato paste around the crust - different and tasty.


On Friday, the 20th, I used my new transit card to get to Seoul. Before leaving, I snapped this picture of a freight truck here --brilliant! It opens on the side, right onto the sidewalk. Why haven't we figured this out in the states...?


I only needed on bus and a short ride on a subway to get to Seoul National University, where a few of my friends from the Korea EAPSI program are studying this summer. 


We went out to an area called Hongdae in Seoul, where we had Mexican food at a little shop called Taco Gusto, which is owned by a guy from New York. Here's a picture of Kelsey, who was my roomie during EAPSI orientation and let me stay with her on Friday night.


Kelsey was really sweet to let me stay with her, especially because her place is itty bitty! I think it's probably a total of 50 square feet. Here she is in her Seoul apartment.


The big destination for Saturday was Kyobo bookstore, which is in the center of Seoul. I wanted to go look at some books in English so I'd have something non-electronic to read while on Baengnyeong Island. It's huge!


The center of Seoul has a large statue of King Sejong, who invented Hangul (Korean). It's the only language for which we know the creator. Also beyond the statue are mountains, ripe for the climbing! I was hoping to get out and do some hiking this past weekend, but we had too much to do!


My Seoul trip concluded with a giant shoot veggie bibimbap at Seoul station. I met up with one of my lab mates, Seongweon, and headed out for Incheon, then Baengnyeong.


We stayed the night at a motel in Incheon so that we could get the 8:20 ferry to Baengnyeong. The ferry ride was about four hours, which I filled with reading my new copy of A Walk in the Woods by Bill Bryson and devouring this pink dino donut from Dunkin' Donuts. Yes, those are frosting covered poprocks!


There was already lots of fog around the islands (we stopped at two others before reaching Baengnyeong), and we almost had to skip the first island because the ferry drivers thought the fog was too thick. 


The islands do have residents, but there is a large military presence. You can see the military bases up on top of the hill here (there was also a cow up there... they must keep them for food).



Once we reached our island, we loaded all our luggage and some scientific equipment into our rental car and the car of the travel agent, who offered to give us a ride, and headed to our motel (the Paradise Motel, spelled out in hangul characters). We got a tasty lunch with something like a shellfish fritatta and shellfish soup - probably the best meal I've tried here, and I don't usually like a lot of shellfish!

Then we drove across the island, which is actually about 30-40 min - it's a big island! The view from the atmospheric research center is great! 




There are TONS of instruments at this site, including this set of 24-hour aerosol samplers across the parking lot from the building.


Behind the atmospheric research center is a meteorology center, with this radar up on top. Taehyoung says he can arrange a tour of that facility tomorrow or the day after.


...And here's the atmospheric research center! It's a very nice building inside, and includes chemical and physical measurements (the most exciting for me include a continuous gas/particle anion/cation ion chromatography instrument, and an x-ray fluorescence instrument that gives continuous concentrations of major metal species. There's also a full wet chemistry lab, and lots of space for our instruments to go!


Here's the AIM (ambient ion monitor) and the continuous metals instrument:


...there are SO many instruments in here!


After stopping at the research center, Taehyoung took us to a really gorgeous beach spread with smooth pebbles. There were lots of perfect skipping stones, so we all skipped and threw stones. Taehyoung told me in Korea they say something like "water bird" to mean skipping stones.



The beach had these colorful umbrellas and I found out today it has some delicious food as well, so hopefully we'll come back here!


Taehyoung also took us to see this beach, which acts as a shortcut for vehicles coming from the city ---you can drive on it at about 30-40 miles per hour!


On day two, there was lots of haze over the island, but not much fog up at the station. The employees told us that the fog doesn't come up to the station as much as it occurs down lower along the coastline, but I'm still hopefully we'll get some good fog water!


The inner part of the island is also really beautiful - there's a lot of agriculture, both in rows on the ground and in large greenhouses.




We unfortunately didn't get our boxes with instruments and lab supplies delivered today as we expected, so I walked around the research station a bit, and wandered up to the meteorology facility Here's a closer view of the radar.


Looking back at the atmospheric research center, you can see the meteorology station that's next to our building as well. I think I'll have plenty of weather data to add to my research up here!


This is going to be a fun experience! I'm loving the island so far - went exploring this evening in the town for a little while after dinner, and everyone is so friendly! Also on the plus side, I have internet in my room so I can keep posting pictures (that is, if I'm not too busy collecting fog water samples!).